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I do use Ventoy, but a more “traditional” alternative that I like is Popsicle. Super lightweight, and works very well. Some cases do require a dedicated USB, where Ventoy won’t work, at least not without trickery (e.g. anything with persistent storage).
I use Syncthing and a bunch of rsync scripts to keep my machines in sync. The stuff I want synced continuously is handled by Syncthing. Other stuff is synced on a daily basis using the rsync scripts and anachron. For Photos, I use PhotoPrism. I simply sync the Photos from my smartphone to a folder and make PhotoPrism scan it on a regular basis using ofelia. For cameras, I need to copy the photos manually, but I don’t think there’s a way around that.